Vinicius Jr came off the bench to score once and set up another goal to steer champions Real Madrid to a 4-1 fightback victory over Espanyol.
The victory saw Spain finish top of League A4 with 11 points after six games, joining France in the final four tournament, which will take place in October 2021.
Luis Suarez grabbed a hat-trick and Lionel Messi bagged two goals as Barcelona began their quest for a third straight La Liga title with a 6-2 rout of Real Betis on Saturday. Arda Turan, whose two goals against Sevilla helped Barca lift the Spanish Super Cup on Wednesday, gave them an early lead at the Nou Camp before Ruben Castro equalised in the 21st minute. Barca went back in front thanks to a trademark 37th-minute goal from Messi before Suarez, La Liga's top scorer last season, made it 3-1 before halftime.
Real Madrid and Barcelona pulled two points clear in La Liga when Cristiano Ronaldo set a club scoring record in Real's 3-0 stroll against Levante and Neymar hit four as Barca beat Rayo Vallecano 5-2 on Saturday.
It was Spain's first competitive win in Portugal since 1934
Bayer Leverkusen beat Freiburg 3-2 to edge closer to a first ever Bundesliga title.
Real Madrid's decision to sell midfielders Xabi Alonso and Angel Di Maria left many scratching their heads and consecutive La Liga defeats as well as a reverse to Atletico Madrid in the Spanish Super Cup set alarm bells ringing at the Bernabeu.
Manchester City suffered from deja vu as Luis Suarez's double gave Barcelona a 2-1 first leg lead in a Champions League last 16 tie at the Etihad although Lionel Messi's late penalty miss left the door ajar on Tuesday.
An under-strength Barcelona got their Champions League campaign off to a solid if unspectacular start when Gerard Pique's header secured a laboured 1-0 win at home to APOEL in their Group F opener on Wednesday.
Italy set up a Euro 2020 semi-final with Spain after first half goals from Nicolo Barella and Lorenzo Insigne led the Azzurri to a 2-1 victory over Belgium on Friday in an entertaining encounter in which both sides created a number of chances.
Barca, who had a rather disappointing season, managed to restore some pride with victory over last season's second division champions in what was the final match to be played at Atletico Madrid's Vicente Calderon Stadium.
Barcelona's stuttering title bid suffered another setback when they lost 2-1 at home to Valencia on Sunday, while Atletico Madrid moved level on points with the La Liga leaders after a comfortable win over Granda.
The last-16 knock-out round kicks-off this week with Chelsea visiting Paris on Tuesday; Zidane to coach Real Madrid as manager in his first match in Europe
Real Madrid are set be thrown out of the Spanish King's Cup after playing banned Russian winger Denis Cheryshev in their last-32 win over Cadiz on Wednesday.
Toni Kroos netted his first for Real Madrid and was hailed as the best player on the pitch by his coach as the hosts tore apart Rayo Vallecano 5-1 in La Liga on Saturday to extend their winning streak to 13 games.
Real Madrid's star striker Cristiano Ronaldo made up for his otherwise quiet night by scoring the winner to beat Barcelona 2-1 win at the CampNou in Barcelona on Saturday.
Chelsea will pay 30 million euros ($33.54 million) for the player, three of which will be based on performance, the Spanish champions said on their website.
Neymar and Lionel Messi grabbed a goal each in the first half as Barcelona rolled over Roma 3-0 in the traditional Gamper Trophy pre-season match on Wednesday.
Lionel Messi scored twice to equal Raul's Champions League scoring record as Barcelona secured their place in the knockout stages by beating 10-man Ajax Amsterdam 2-0 on Wednesday.
Pep Guardiola says Manchester City are not yet ready to compete with Europe's elite but his side will be confident of opening their Champions League campaign with victory over Borussia Moenchengladbach on Tuesday.
Barcelona won the La Liga title with a comfortable 3-0 victory at Granada thanks to a Luis Suarez hat-trick in the season finale on Saturday.
A round-up of Wednesday's action in the UEFA Champions League
World champions France won the Nations League final with goals from Karim Benzema and Kylian Mbappe earning them a 2-1 win over Spain at the San Siro stadium on Sunday.
Images from football friendlies played on Wednesday.
Luis Suarez has progressed from his impressive debut La Liga campaign to produce the most prolific season of his career and fire Barcelona to a second straight title, free of the stigma of his ban for biting which accompanied him to Spain in 2014. It was fitting that the Uruguayan should score a hat-trick in the comfortable 3-0 victory at Granada on Saturday to clinch the title, taking his tally to 40 goals in 35 games. He is the first player other than Cristiano Ronaldo and Lionel Messi to finish as La Liga top scorer since 2009 but his contribution to Barca's title triumph goes beyond his goals and 16 assists. For Suarez is the hardest working of the feted 'MSN' partnership he forms with Messi and Neymar, a trio who have delivered 90 of Barcelona's 112 league goals. He is also the most willing to close down opponents and run into space and, naturally, he has shown himself to be the player who is keenest to throw himself into any physical battle.
Barcelona will put Manchester City to the sword if they commit the same kind of errors as they did in their Champions League encounter last month, coach Luis Enrique said.
Luis Suarez scored a hat-trick and Lionel Messi bagged a brace as Barcelona thrashed bottom side Cordoba 8-0 on Saturday to move a step closer to their fifth La Liga title in seven years.
Lionel Messi notched his 250th La Liga goal to move one off the all-time league scoring record as leaders Barcelona won 3-0 against Eibar on Saturday ahead of next weekend's Clasico with Real Madrid.
Barcelona midfielder Ivan Rakitic embraced the art of winning ugly after they beat 10-man Real Betis 2-0 to move closer to retaining their La Liga title.
Barcelona coach Gerardo Martino resigned on Saturday after just one season in charge having finished second to Atletico Madrid in the La Liga title race and failed to win a major trophy.
After an almighty push by all parties concerned, Spain's La Liga roars back into action next week after a three-month pause due to the COVID-19 pandemic, with matches taking place every day and with everything to play for. The season resumes on Wednesday in bizarre circumstances with the second half of a Segunda Division match between Rayo Vallecano and Albacete that was abandoned in December due to offensive chanting.
Barcelona squandered the chance to go 11 points clear in La Liga on Sunday after blowing a two-goal lead in the space of six minutes in a 2-2 draw at Villarreal overshadowed by a controversial penalty.
Manchester United should sack Louis Van Gaal and install his assistant Ryan Giggs as manager, according to former striker Dwight Yorke who wants to launch his own managerial career at struggling Aston Villa. The former Trinidad and Tobago striker said changes were needed at United, with the 20-times English champions sixth in the Premier League, out of the Champions League and suffering a 2-0 loss to arch-rivals Liverpool in the Europa League this week. "At the end of the day, it's all about results," Yorke was quoted as saying by Singaporean daily The New Paper on Saturday after a promotional event in the Southeast Asian citystate. "In the two years that he's (Van Gaal) been there, he's spent tons of money, brought in tons of players, and simply hasn't got the results that he and everyone else had hoped to. "You see a lot of young managers, Zinedine Zidane's been given the opportunity at Real Madrid, you got Luis Enrique at Barcelona, Pep Guardiola who's coming to Manchester City, Tottenham's Mauricio Pochettino, they're all ex-players. "And I feel that the game is going down that road, and maybe this is the right time to give Giggsy the job." Yorke won three Premier League titles and the 1999 Champions League with United under former manager Alex Ferguson after joining from Aston Villa.
Paris St Germain coach Unai Emery cursed his side for switching off in the final minutes of their 6-1 defeat at Barcelona which sent the French champions out of the Champions League before the quarter-finals for the first time in five years.
Barcelona will be missing the lethal touch of Neymar in attack for the UEFA Super Cup against Sevilla.
Lionel Messi became the first player to notch 300 La Liga goals as his double blast powered Barcelona to a 3-1 win at Sporting Gijon that sent them six points clear at the top of the table on Wednesday.
Luis Suarez and Lionel Messi scored stunning goals to edge Barcelona towards a fourth consecutive King's Cup final with a 2-1 win at Atletico Madrid on Wednesday, although the holders were lucky to survive a late onslaught from the hosts.
Barcelona dealt a stinging blow to Real Madrid's title hopes when Luis Suarez and Neymar continued their scintillating form to fire the champions to a stunning 4-0 victory in the La Liga 'Clasico' on Saturday.
Xavi's agent has declined to comment on reports the Barcelona midfielder is set to leave the La Liga leaders at the end of the season and sign a lucrative contract with Qatari side Al Sadd.
IMAGES from the Champions League matches played on Tuesday.